Extreme 32GB not recognized as removable storage

“Do I have a faulty unit,”

No, it was designed that way to support a Microsoft Windows 8 requirement.  However, SanDisk has stopped making them that way.  See  http://forums.sandisk.com/t5/All-SanDisk-USB-Flash-Drives/Models-configured-for-Fixed-Disk/m-p/306011#M6244

“is there a firmware update to fix this,”

No.

“will I have to RMA my stick?”

Yes, or return it to seller.

See if this helps you create a bootable flash drive: http://www.techsupportalert.com/content/create-bootable-usb-key-thumb-drive-windows-vista7-command-line.htm